Why does Isabella enter the Abyss?

She volunteers as a sacrifice to save her stepsister from the Abyss's demand.

The fallen angel the world fears, bound to Isabella after she enters the Abyss.

Angel Sacrificed to the Abyssal Demon

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Angel Sacrificed to the Abyssal Demon — A pureblood angel sacrifices herself to a fallen angel after betrayal by her archangel lover.

Isabella endures exploitation from a family that murdered her mother and favors her stepsister. When the Abyss demands a tribute, she volunteers to spare her sibling, binding herself to Azriel, the fallen angel humanity dreads. She discovers her beloved, Archangel Sebastian, manipulated her solely to shield her stepsister. Humiliated and cast down, Isabella enters the Abyss expecting death but encounters a wounded Azriel whose darkness requires her innate radiance. Their forced proximity shifts from obligation to a fragile connection as she realizes her light may be the only force capable of mending his shattered existence.

Quick answers

Why does Isabella enter the Abyss?: She volunteers as a sacrifice to save her stepsister from the Abyss's demand.
Who is Azriel?: The fallen angel the world fears, bound to Isabella after she enters the Abyss.