What privilege did the patriarch grant Chloe?

The right to choose one of his five sons as a husband.

Who turns the brothers against Chloe?

Luna, an adopted sister motivated by jealousy.

No to Five Heirs, Yes to a Billionaire

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No to Five Heirs, Yes to a Billionaire — A medical prodigy saves a patriarch and wins the right to choose a husband from his five sons, only to suffer years of sabotage.

Chloe enters the powerful Lu household as a child and matures into a physician whose skill rescues the dying family head. In gratitude, the patriarch grants her the unprecedented privilege of selecting one of his five sons as a future spouse. She spends the next ten years providing unpaid medical care to the entire family. Meanwhile, Luna, another adopted daughter driven by envy, spreads malicious falsehoods that poison every brother's opinion. The sons accept Chloe's healing while treating her with contempt, exploiting her devotion and dismissing her sincere service.

Quick answers

What privilege did the patriarch grant Chloe?: The right to choose one of his five sons as a husband.
Who turns the brothers against Chloe?: Luna, an adopted sister motivated by jealousy.