What happened to Valentina's sister in the first timeline?

She married into the Greco family, was locked in a dungeon as a blood slave for the Godfather's mistress, tortured to death, and their family was wiped out.

What does Valentina do immediately after rebirth?

On her engagement night, she takes the marriage contract and walks straight to Don Alessandro to seek justice for her sister.

The Cursed Girl Who Married the Mafia Don

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The Cursed Girl Who Married the Mafia Don — A woman branded a curse uses a second life to infiltrate the mafia household that destroyed her family.

Valentina has always been treated as a bad omen by her relatives, finding kinship only with her sister. In a previous timeline, that sister married into the Greco mafia clan and was imprisoned in a dungeon, forced to serve as a blood source for the Godfather's mistress until torture killed her and wiped out their kin. Returning to the evening of her own arranged engagement, Valentina seizes the marriage contract and approaches Don Alessandro deliberately, intending to rewrite the tragedy from inside the organization.

Quick answers

What happened to Valentina's sister in the first timeline?: She married into the Greco family, was locked in a dungeon as a blood slave for the Godfather's mistress, tortured to death, and their family was wiped out.
What does Valentina do immediately after rebirth?: On her engagement night, she takes the marriage contract and walks straight to Don Alessandro to seek justice for her sister.