Who is Ronan in relation to Miles?

Ronan is Miles's older brother and a dangerous gangster.

What triggers Ronan's interest in Emery?

An accident brings Emery to Ronan's attention, leading him to repeatedly protect her.

The Mafia Brother I Shouldn’t Love

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The Mafia Brother I Shouldn’t Love — A woman's hidden affection for her childhood friend collides with the ruthless protection of his gangster brother.

Emery has spent ten years concealing her feelings for Miles, watching him remain fixated on his ex-girlfriend Celeste. An unexpected accident pulls her into the orbit of Ronan, Miles's older brother and a formidable gangster who intervenes repeatedly to keep her safe. As Ronan's intense guardianship deepens, Emery faces a stark divide: the steady, unrequited bond she cherished with Miles versus a volatile, high-stakes connection with a man who operates outside the law. Her attempt to finally release her quiet longing for Miles only tightens Ronan's hold, pulling her further into a world where affection and danger are inseparable.

Quick answers

Who is Ronan in relation to Miles?: Ronan is Miles's older brother and a dangerous gangster.
What triggers Ronan's interest in Emery?: An accident brings Emery to Ronan's attention, leading him to repeatedly protect her.